I do have MSI Afterburner in the background but besides that there are no more software open. Only other thing that is open during this is a fan controller app.
As you can see from the image below, I had HWiNFO64 open and minimized to tray for a while. Wasn't playing games or anything but when I opened it back up it showed that the Maximum CPU Die (Average) was 104.2c. How could this be possible? As you can see from my other temps from the sensors...