Had the same issue with the AMD raptr program. Gets past the videos and it crashes - acs.exe error. I can close it and then load HWiNFO in game and it runs fine, but its a pain. Dunno what to try, let me know - thank you so much!
Well, this is a really odd issue. But since the game is crushing, you should submit the problem to them.
Otherwise I don't know what to suggest, perhaps try to disable monitoring of some sensors in HWiNFO, but I'm not sure if that will change anything..