On the HWiNFO64 screenshot I can see that there are 36 sensor values hidden (by user).
So please try check sensor settings whether those you're missing might be hidden, alternatively you might try to do a "Reset Preferences" or "Restore Original Order".
Machine-specific settings like hidden sensors are not stored in the INI file, but in the registry instead.
And there are different paths in registry for HWiNFO32 and HWiNFO64.